Putting Quantum dots to work

Quantum dots apart from being neat things in and of themselves-could be put to some very interesting uses. The first application of quantum dots will be for biological labels used in medical imaging. Researchers tag proteins and nucleic acids with quantum dots. When they shine ultraviolet ray on the sample, the quantum dots glow at a specific wavelength and indicate the locations of attached proteins. Quantum dots have advantages over materials currently used for this application. For example they glow longer.

Researchers are also hoping that quantum dots could eventually provide energy efficient lighting for general use, in your house, office or neighborhood street lamps. In these applications a light emitting diode (LED) or other source of UV light would shine on quantum dots, which would then light up. By mixing different sizes (and the associated colors) of quantum dots together, you could generate white light. Generating light from quantum dots would work like generating fluorescent light but without the bulky fluorescent tube. This method would also avoid the wasted heat that you get with your typical incandescent light bulb.

Passing an electrical current through an LED also generates light. A company called Q vision is attempting to use techniques developed MIT to design a quantum dot LED: A layer of quantum dots sandwiched between conductive organic layers. Passing a c

Flat panel TV displays using quantum dots LEDs may provide more vibrant colors than current flat panel displays based on liquid crystals Display (LCD) Technology.

urrent through the dots generates light

Getting quantum dot energized

Quantum dots are useful because when you add energy to their electrons, the electrons act they’re in one big atom.- and (as any physicist could tell you) When you add electrons in any atom, what you get is light. This occurs hen an electron moves to a higher energy level and then falls back again to it’s normal energy level. The same is true for quantum dots – zap them they will glow. One way to add energy to quantum dots is to shine an ultraviolet light on them

It turns that the smaller the quantum dot, larger the gap between energy levels. Which means more energy is packed into photons – which means more energy is packed into the photon that’s emitted when an electron falls from a higher energy level to it’s normal energy level.A small quantum dot emits higher energy photons – with a shorter wavelength than a large Q-dot can.
Think of this light in terms of color: a quantum dot of a particular size- a relatively larger size, to be exact- emits red light, which is the longest wave length of visible light: smaller quantum dots produce different colors. If you keep going smaller and smaller, you’ll eventually get to a tiny quantum dots that produce blue light.- the shortest wavelength of visible light. If you come up with really large quantum dots you might get them to emit infrared light: incredibly teensy quantum dots might emit ultra violet light, outside the visible spectrum.

So where do you get quantum dots (No you cant find them in one stop shops store at least not yet) It turns out that it is possible to grow a large number of quantum dots in a chemical reactions. But the methods used range from simple wet –chemical setups. (In which you precipitate zinc sulphide crystals) to complicate methods such as chemical-vapor deposition.(Which is also used to grow carbon Nanotubes). You can control the size of the particular batch of quantum dots- ensuring that they all emit the same wavelength of light- by controlling the length of time you allow the reaction to run. But what do you do with them once you have got them?

Artificial atoms

The three-dimensional (3D) spherically symmetric potential around atoms yields degeneracies known as shells, 1s, 2s, 3s, 3p,... Each shell can hold a specific number of electrons. The electronic configuration is particularly stable when these shells are completely filled wih electrons, occurring at 'magic' atomic numbers 2, 10, 18, 36,... In a similar way, the symmetry of a two-dimensional (2D), disk-shaped quantum dot leads to a shell structure with magic numbers 2, 6, 12, 20,... The lower degree of symmetry in 2D results in a different sequence of magic numbers than in 3D.

By measuring electron transport through quantum dots, a periodic table of artificial 2D elements can be obtained. For this purpose, dots are connected via potential barriers to source and drain contacts. If the barriers are thick enough , the number of electrons on the dot, N, is a well defined integer. This number changes when electrons tunnel to and from the dot. However, due to Coulomb repulsion between electrons, the energy of a dot containing N+1 electrons is larger than when it contains N electrons. Extra energy is therefore needed to add an electron to the dot. Consequently, no current can flow which is known as the Coulomb blockade.

The blockade can be lifted by means of a third electrode closeby, known as the gate contact. A negative voltage applied to this gate is used to supply the extra energy and thereby change the number of free electrons on the dot. This makes it possible to record the current flow between source and drain as the number of electrons on the dot, and hence its energy, is varied. The Coulomb blockade leads to a series of sharp peaks in the measured current (see figure below). At any given peak, the number of electrons on the dot alternates between N and N+ 1. Between the peaks, the current is zero and N remains constant. The distance between consecutive peaks is proportional to the so-called addition energy, which is the difference in energy between dots with N+1 and N electrons. The magic numbers can be identified because significantly higher voltages are needed to add the 2nd, 6th and 12th electron.

Quantum dots are 2D analogies for real atoms. But since they have much larger dimensions they are suitable for experiments that can not be carried out in atomic physics. It is especially interesting to observe the effect of a magnetic fieldd, B, on the atom-like properties. A magnetic flux-quantum in an atom requires typically a B-field as high as 10^6 T, whereas for dots this is of the order 1 T, which is experimentally accessible.

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